advanced rendering for AutoCAD
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Roy may have better guidance, but this is as I understand it.
Create a glass material and under Transparency, set Dispersion and Saturation to 1.0.
Also a high IOR such as 1.6 will help.
You'll have to post an example. Start with a picture. It will help me determine whether we've got a solution for the particular application.
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Somewhere I've got a prism model that I used when designing the effect.